Rail cars can carry pressurized and unpressurized liquids, pressurized and refrigerated gases, and solids. Types of rail cars that typically carry hazardous materials are shown and described below. Hazardous commodities transported in rail cars must be identified by markings, placards, and shipping papers.
To identify the hazardous materials carried in a rail car, check for:
The train consist A document showing the current positions within a train of cars carrying hazardous materials.. This document is carried by the train crew, and also should be in the company's computer system. It lists all cars in the train and the current positions of cars carrying hazardous materials.
Waybills. A waybill is issued for each rail car. It lists the shipper, consignee, and car contents. Waybills should be kept by the conductor.
Stenciling. For certain chemicals, the name of the hazardous material in the rail car is stenciled on both sides. Example:
As the stenciled name shows, this tank car carries liquified petroleum gas, or LPG.
Placards. Placards on the rail car indicate the substance's main hazard and also display the UN/NA number United Nations-North America number. (Also UN Number or DOT Number.) Four-digit number identifying an individual chemical or group of chemicals with similar characteristics. Required on shipping papers; often shown on placards or labels. Often preceded by "UN": e.g., "UN1219.". Example: Note that placards may be missing, and rail cars may be incorrectly placarded. Where to look for placards:
The DOT placard with UN/NA number United Nations-North America number. (Also UN Number or DOT Number.) Four-digit number identifying an individual chemical or group of chemicals with similar characteristics. Required on shipping papers; often shown on placards or labels. Often preceded by "UN": e.g., "UN1219." (1824) is visible on this derailed tankcar.

Look for identical diamond-shaped placards on the front, rear, and both sides of the rail car.
On the placard, look for the UN/NA number United Nations-North America number. (Also UN Number or DOT Number.) Four-digit number identifying an individual chemical or group of chemicals with similar characteristics. Required on shipping papers; often shown on placards or labels. Often preceded by "UN": e.g., "UN1219.". (Some placards display only the substance's hazard class One of 9 categories of hazardous materials. The hazard class indicates the most important hazard of a given material (e.g., "Explosives," "Poison Gas"). While some materials meet the criteria for more than one class, each material is assigned just one class or division label, not the UN/NA number. When UN/NA numbers are not on placards, check shipping papers or container labels.)
Look up the UN/NA number in CAMEO Chemicals or in the Emergency Response Guidebook to learn the substance's
name and see response recommendations.
Reporting marks. Each rail car is identified by a unique reporting mark: a combination of letters followed by numbers that is stenciled on both sides and both ends of the car. The sequence of letters identifies the railroad or company that owns the car, and the sequence of numbers identifies the car. As you face the side of the car, the reporting mark is to your left. You can call a car's reporting marks into CHEMTREC (800) 424-9300) to identify the car's owner and, eventually, its contents. Example reporting mark:

DOT Tank car specification markings. These markings, on both sides of the car, identify the class of tank car, which tells you what it could be carrying. Decoding a specification marking:
The first sequence of numbers (111 in the example below) tells you the car's class: non-pressure, pressure, high pressure, or cryogenic.

Use as many information sources
as you can! Why and how?
Shipping documents, labels, and placards sometimes contain errors. Chemical names are often misspelled on shipping documents, and a small difference of a letter or two can make a big difference. For example, sulfide and sulfate refer to chemicals that greatly differ in hazardousness. ID numbers can be incorrect, labels can be faded or torn, and placards may be missing.
To catch such problems:
Check more than one source of information. For example, review the DCM Dangerous Cargo Manifest. Listing of the hazardous materials and substances transported on a vessel or barge as well as the cargo manifest Document describing the contents of a shipment, checking for differences in name spellings and ID numbers.
Check that the identifiers for a chemical match. For example, check that the shipping name Or Proper shipping name. Either: (a) the specific name of a hazardous material that is frequently shipped (e.g., "Ammonia, anhydrous"), or (b) the generic name for a less frequently shipped hazardous material, which categorizes the material by its family, its use, or a key characteristic (e.g., "Acids, n.o.s. (Not Otherwise Indicated)," "Flammable solids, n.o.s.") and the UN/NA number United Nations-North America number. (Also UN Number or DOT Number.) Four-digit number identifying an individual chemical or group of chemicals with similar characteristics. Required on shipping papers; often shown on placards or labels. Often preceded by "UN": e.g., "UN1219." are for the same chemical. One quick way to do this: use both the name and number to search CAMEO Chemicals for the chemical's data sheet.
Finally, contact your SSC whenever you need help from expert hazmat chemists.
Once you've found identifiers Names, ID numbers, and other information used to identify a chemical for the commodity, you can look up its data sheet in CAMEO Chemicals (opens in new window).
Click any silhouette to see a description of that type of rail car and its possible contents:
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Also see the section on Intermodal containers, which are commonly carried on rail flatcars.
Typically carries pressurized flammable gases (e.g., propane, liquified petroleum gas), poisonous gases (e.g., chlorine, sulfur dioxide, vinyl chloride), or nonflammable gases (e.g., argon, carbon dioxide).
Includes car classes DOT105, DOT109, DOT112, DOT114, DOT120.
Round in cross section. Capacity up to 33,500 gallons; pressure 100 to 600 psi pounds per square inch; a unit of pressure measurement. Generally steel or aluminum.
A cylindrical protective housing at top of car encloses valves and piping. Most tank cars carrying pressurized flammable gases are insulated.

Typically carries chemicals such as combustible or flammable liquids (e.g., gasoline, fuel oil), corrosives, oxidizers and organic peroxides, slurries, or poisons, or food liquids (e.g., juice, tomato paste, tallow).
Cannot transport substances classified as inhalation hazards in the Hazardous Materials Table (49 CFR 172.101).
Includes car classes DOT103, DOT104, DOT111, DOT115, AAR201, AAR203, AAR206, AAR211.
Round in cross-section. Capacity up to 30,000 gallons. May be compartmentalized and/or insulated. Pressure can be up to 100 psi.
Valves and fittings are exposed. Often, a small dome cover is located at the top of the car, but relief valves and piping are outside of this cover.

Carries gases such as oxygen, helium, hydrogen, nitrogen in high-pressure cylinders.

Typically contains gases liquified by refrigeration, such as liquid hydrogen and nitrogen.
Pressure within tank is low; temperature is -130 degrees F or below. Tank is generally double walled and insulated. Test pressures from 60 to 175 psi pounds per square inch; a unit of pressure measurement.
Valves and fittings are enclosed in a cabinet at the lower side or end of the car.
Includes car classes DOT113, AAR204W, AAR204XT.
Typically contains dry bulk chemicals such as calcium carbide, sodium chlorate, ammonium nitrate, lime, other dry chemicals; also sand, gravel, fertilizers, plastic pellets.
Hopper cars may be covered or open top.

Typically contains mixed cargo, which may be packed in bags, boxes, drums, tanks, cylinders, liquid bladders, or other containers. Check labels and tags on individual containers to identify their contents.
Car class AAR204XT is a box car carrying a cryogenic very low temperature tank.
